The geographical elementary school lines were recently changed for the 2012 - 2013 school year in New Canaan. If you're looking at a property listing, the elementary school is listed for that particular property. There is only one middle school in New Canaan (as in Darien) so there is no question about the middle or high school.
Here is the New Canaan School's link so that if you have a question, you can find out on your own:
http://www2.newcanaan.k12.ct.us/education/components/scrapbo or you can email or call me and I can give you a quick response.
You could also request a bus route map, which would also give you the street / school connection. That was published by The New Canaan Advertiser in August, or again, by calling one of the elementary schools. In New Canaan, they are South, West and East School. In Darien, they are Ox Ridge, Rpyle, Holmes, Hindley and Tokeneke School.
I'm happy to answer any other questions you may have.
William Pitt | Sotheby's International Realty
26 Cherry Street
New Canaan, CT 06840
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